| Literature DB >> 20574561 |
Melanie Zimmermann1, Dorothea Rauschmaier, Klaus Eichele, Karl W Törnroos, Reiner Anwander.
Abstract
Donor(thf)-induced tetramethylaluminate cleavage of Ln(AlMe(4))(2)(NSiMe(3)Ar(iPr)) as well as the reaction of (LnMe(3))(n) (Ln = Y, Ho, Lu) with HNSiMe(3)Ar(iPr) in tetrahydrofuran affords unprecedented trinuclear rare-earth metal tetramethyl methylidene complexes which act as Schrock-type nucleophilic carbenes and methyl transfer agents.Entities:
Year: 2010 PMID： 20574561 DOI： 10.1039/c003206a
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222