Literature DB >> 20572216

Homogeneous gold catalysis beyond assumptions and proposals--characterized intermediates.

A Stephen K Hashmi1.   

Abstract

Gold catalysis is a very active area in the field of catalysis research. New reactions are published every week, amazing changes in the connectivity are often observed, the number of applications in total synthesis is increasing...--but what are the mechanisms of these reactions? Sound information can be provided by knowledge about the intermediates of these reactions.

Year:  2010        PMID： 20572216     DOI： 10.1002/anie.200907078

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  65 in total

1.  Strong electronic and counterion effects on geminal digold formation and reactivity as revealed by gold(I)-aryl model complexes.

Authors:  Dieter Weber; T David Jones; Laura L Adduci; Michel R Gagné
Journal:  Angew Chem Int Ed Engl       Date:  2012-01-25       Impact factor: 15.336

2.  Investigations on Gold-Catalyzed Thioalkyne Activation Toward Facile Synthesis of Ketene Dithioacetals.

Authors:  Xiaohan Ye; Jin Wang; Shengtao Ding; Seyedmorteza Hosseyni; Lukasz Wojtas; Novruz G Akhmedov; Xiaodong Shi
Journal:  Chemistry       Date:  2017-07-20       Impact factor: 5.236

3.  Mechanistic Studies of Gold and Palladium Cooperative Dual-Catalytic Cross-Coupling Systems.

Authors:  Mohammad Al-Amin; Katrina E Roth; Suzanne A Blum
Journal:  ACS Catal       Date:  2014-02-07       Impact factor: 13.084

4.  Rhodium-catalyzed intra- and intermolecular [5 + 2] cycloaddition of 3-acyloxy-1,4-enyne and alkyne with concomitant 1,2-acyloxy migration.

Authors:  Xing-Zhong Shu; Xiaoxun Li; Dongxu Shu; Suyu Huang; Casi M Schienebeck; Xin Zhou; Patrick J Robichaux; Weiping Tang
Journal:  J Am Chem Soc       Date:  2012-03-12       Impact factor: 15.419

Review 5.  Transition metal-mediated synthesis of monocyclic aromatic heterocycles.

Authors:  Anton V Gulevich; Alexander S Dudnik; Natalia Chernyak; Vladimir Gevorgyan
Journal:  Chem Rev       Date:  2013-01-10       Impact factor: 60.622

6.  Direct Evidence for the Origin of Bis-Gold Intermediates: Probing Gold Catalysis with Mass Spectrometry.

Authors:  Mei Lu; Yijin Su; Pengyi Zhao; Xiaohan Ye; Yi Cai; Xiaodong Shi; Eric Masson; Fengyao Li; J Larry Campbell; Hao Chen
Journal:  Chemistry       Date:  2018-01-17       Impact factor: 5.236

7.  Mechanistic analysis of gold(I)-catalyzed intramolecular allene hydroalkoxylation reveals an off-cycle bis(gold) vinyl species and reversible C-O bond formation.

Authors:  Timothy J Brown; Dieter Weber; Michel R Gagné; Ross A Widenhoefer
Journal:  J Am Chem Soc       Date:  2012-05-29       Impact factor: 15.419

8.  Mechanism of AuCl₃-catalyzed cyclization of 1-(indol-2-yl)-3-alkyn-1-ols: a DFT study.

Authors:  Jingna Shao; Rongxing He; Wei Shen; Ming Li
Journal:  J Mol Model       Date:  2014-05-07       Impact factor: 1.810

9.  Gold-catalyzed diastereoselective cycloisomerization of alkylidene-cyclopropane-bearing 1,6-diynes.

Authors:  Hongchao Zheng; Laura L Adduci; Ryan J Felix; Michel R Gagné
Journal:  Angew Chem Int Ed Engl       Date:  2014-06-11       Impact factor: 15.336

10.  Generation of rhodium(I) carbenes from ynamides and their reactions with alkynes and alkenes.

Authors:  Renhe Liu; Gabrielle N Winston-McPherson; Zhong-Yue Yang; Xin Zhou; Wangze Song; Ilia A Guzei; Xiufang Xu; Weiping Tang
Journal:  J Am Chem Soc       Date:  2013-05-23       Impact factor: 15.419
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