Reactivity of an aryl-substituted silicon-silicon triple bond: 1,2-disilabenzenes from the reactions of a 1,2-diaryldisilyne with alkynes.

The reactivity of a diaryl-substituted disilyne, Ar-Si[triple bond, length as m-dash]Si-Ar, with alkynes was examined. Reaction of the disilyne with acetylene yielded a 1,2-disilabenzene as the sole product.