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Literature DB >> 20568750

Gold(I)-catalyzed intermolecular [2+2] cycloaddition of alkynes with alkenes.

Verónica López-Carrillo¹, Antonio M Echavarren.

Abstract

The gold(I)-catalyzed intermolecular reaction of terminal alkynes with alkenes leads to cyclobutenes. The use of sterically hindered cationic Au(I) complexes as catalysts is key for the success of this reaction.

Entities: Chemical

Year: 2010 PMID： 20568750 DOI： 10.1021/ja104177w

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

26 in total

1. Nickel-Catalyzed Reductive [2+2] Cycloaddition of Alkynes.

Authors: Santiago Cañellas; John Montgomery; Miquel À Pericàs
Journal: J Am Chem Soc Date: 2018-12-10 Impact factor: 15.419

2. Gold(I)-catalyzed diastereo- and enantioselective 1,3-dipolar cycloaddition and Mannich reactions of azlactones.

Authors: Asa D Melhado; Giovanni W Amarante; Z Jane Wang; Marco Luparia; F Dean Toste
Journal: J Am Chem Soc Date: 2011-02-22 Impact factor: 15.419

3. Catalytic Enantioselective Synthesis of Cyclobutenes from Alkynes and Alkenyl Derivatives.

Authors: Mahesh M Parsutkar; Vinayak Vishnu Pagar; T V RajanBabu
Journal: J Am Chem Soc Date: 2019-09-12 Impact factor: 15.419

4. Enantioselective construction of α-quaternary cyclobutanones by catalytic asymmetric allylic alkylation.

Authors: Corey M Reeves; Christian Eidamshaus; Jimin Kim; Brian M Stoltz
Journal: Angew Chem Int Ed Engl Date: 2013-05-17 Impact factor: 15.336

5. Ring expansion of alkynyl cyclopropanes to highly substituted cyclobutenes via a N-sulfonyl-1,2,3-triazole intermediate.

Authors: Renhe Liu; Min Zhang; Gabrielle Winston-McPherson; Weiping Tang
Journal: Chem Commun (Camb) Date: 2012-08-03 Impact factor: 6.222

10. Formal (4+1) cycloaddition of methylenecyclopropanes with 7-aryl-1,3,5-cycloheptatrienes by triple gold(I) catalysis.

Authors: Yahui Wang; Michael E Muratore; Zhouting Rong; Antonio M Echavarren
Journal: Angew Chem Int Ed Engl Date: 2014-06-04 Impact factor: 15.336

Gold(I)-catalyzed intermolecular [2+2] cycloaddition of alkynes with alkenes.

1. Nickel-Catalyzed Reductive [2+2] Cycloaddition of Alkynes.

2. Gold(I)-catalyzed diastereo- and enantioselective 1,3-dipolar cycloaddition and Mannich reactions of azlactones.

3. Catalytic Enantioselective Synthesis of Cyclobutenes from Alkynes and Alkenyl Derivatives.

4. Enantioselective construction of α-quaternary cyclobutanones by catalytic asymmetric allylic alkylation.

5. Ring expansion of alkynyl cyclopropanes to highly substituted cyclobutenes via a N-sulfonyl-1,2,3-triazole intermediate.

6. Au-Catalyzed Intermolecular [2+2] Cycloadditions between Chloroalkynes and Unactivated Alkenes.

7. Recent developments in gold-catalyzed cycloaddition reactions.

8. Dissecting Anion Effects in Gold(I)-Catalyzed Intermolecular Cycloadditions.

9. Gold-Catalyzed Reactions via Cyclopropyl Gold Carbene-like Intermediates.

10. Formal (4+1) cycloaddition of methylenecyclopropanes with 7-aryl-1,3,5-cycloheptatrienes by triple gold(I) catalysis.