Ligational, analytical and biological applications on oxalyl bis(3,4-dihydroxybenzylidene) hydrazone.

The molecular modeling and parameters have been calculated to confirm the geometry of oxalyl bis(3,4-dihydroxybenzylidene) hydrazone, H(6)L. The metal complexes of Cr(3+), VO(2+), ZrO(2+), HfO(2+), UO(2)(2+) and MoO(2)(2+) with H(6)L have been prepared and characterized by partial elemental analysis, spectral studies (electronic; IR), thermal analysis and magnetic measurements. The data suggest the formation of polymer complexes with a unit [Cr(H(4)L)(H(2)O)(3)Cl].H(2)O, [VO(H(4)L)(H(2)O)(2)], [Hf(H(4)L)(H(2)O)].H(2)O [UO(2)(H(4)L)(H(2)O)(2)].2H(2)O [MoO(2)(H(4)L)] and [(ZrO)(2)(H(2)L)-(C(2)H(5)OH)(2)]. The ligand behaves as a dibasic bidentate in all complexes except ZrO(2+) which acts as a tetrabasic tetradentate with the two ZrO(2+) ions. An octahedral geometry was proposed for the Cr(3+), HfO(2+), MoO(2)(2+)and UO(2)(2+) complexes and square pyramid for VO(2+). The Cr(3+) is necessary to degrade the DNA of eukaryotic subject completely; the other complexes have little effect. H(6)L was found suitable as a new reagent for the separation and preconcentration of ZrO(2+) ions from different water samples using flotation technique with satisfactory results. Copyright 2010 Elsevier B.V. All rights reserved.