Literature DB >> 20540579

An efficient nickel catalyst for the reduction of carbon dioxide with a borane.

Sumit Chakraborty1, Jie Zhang, Jeanette A Krause, Hairong Guan.   

Abstract

Nickel hydride with a diphosphinite-based ligand catalyzes the highly efficient reduction of CO(2) with catecholborane, and the hydrolysis of the resulting methoxyboryl species produces CH(3)OH in good yield. The mechanism involves a nickel formate, formaldehyde, and a nickel methoxide as different reduced stages for CO(2). The reaction may also be catalyzed by an air-stable nickel formate.

Entities:  

Mesh：

Substances：

Year:  2010        PMID： 20540579     DOI： 10.1021/ja103982t

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  13 in total

1.  Nickel hydrides supported by a non-innocent diphosphine arene pincer: mechanistic studies of nickel-arene H-migration and partial arene hydrogenation.

Authors:  Sibo Lin; Michael W Day; Theodor Agapie
Journal:  J Am Chem Soc       Date:  2011-02-23       Impact factor: 15.419

2.  Trialkylborane-Assisted CO(2) Reduction by Late Transition Metal Hydrides.

Authors:  Alexander J M Miller; Jay A Labinger; John E Bercaw
Journal:  Organometallics       Date:  2011       Impact factor: 3.876

3.  Insight into catalytic reduction of CO2 to methane with silanes using Brookhart's cationic Ir(iii) pincer complex.

Authors:  Shaoqin Fang; Hongcai Chen; Haiyan Wei
Journal:  RSC Adv       Date:  2018-03-02       Impact factor: 4.036

Review 4.  Homogeneous Catalysis for Sustainable Energy: Hydrogen and Methanol Economies, Fuels from Biomass, and Related Topics.

Authors:  Amit Kumar; Prosenjit Daw; David Milstein
Journal:  Chem Rev       Date:  2021-11-02       Impact factor: 60.622

5.  Carbon Dioxide Utilization by the Five-Membered Ring Products of Cyclometalation Reactions.

Authors:  Iwao Omae
Journal:  Curr Org Chem       Date:  2016-04       Impact factor: 2.180

6.  Formylation or methylation: what determines the chemoselectivity of the reaction of amine, CO2, and hydrosilane catalyzed by 1,3,2-diazaphospholene?

Authors:  Yu Lu; Zhong-Hua Gao; Xiang-Yu Chen; Jiandong Guo; Zheyuan Liu; Yanfeng Dang; Song Ye; Zhi-Xiang Wang
Journal:  Chem Sci       Date:  2017-09-11       Impact factor: 9.825

7.  Controlling the Product Platform of Carbon Dioxide Reduction: Adaptive Catalytic Hydrosilylation of CO2 Using a Molecular Cobalt(II) Triazine Complex.

Authors:  Hanna H Cramer; Basujit Chatterjee; Thomas Weyhermüller; Christophe Werlé; Walter Leitner
Journal:  Angew Chem Int Ed Engl       Date:  2020-06-02       Impact factor: 15.336

8.  Hydrogenation of carbon dioxide to methanol using a homogeneous ruthenium-Triphos catalyst: from mechanistic investigations to multiphase catalysis.

Authors:  Sebastian Wesselbaum; Verena Moha; Markus Meuresch; Sandra Brosinski; Katharina M Thenert; Jens Kothe; Thorsten Vom Stein; Ulli Englert; Markus Hölscher; Jürgen Klankermayer; Walter Leitner
Journal:  Chem Sci       Date:  2014-08-27       Impact factor: 9.825

9.  Synthesis and Characterization of Dimethylbis(2-pyridyl)borate Nickel(II) Complexes: Unimolecular Square-Planar to Square-Planar Rotation around Nickel(II).

Authors:  Jeff A Celaje; Megan K Pennington-Boggio; Robinson W Flaig; Michael G Richmond; Travis J Williams
Journal:  Organometallics       Date:  2014-04-07       Impact factor: 3.876

10.  Manganese-catalyzed hydroboration of carbon dioxide and other challenging carbonyl groups.

Authors:  Christina Erken; Akash Kaithal; Suman Sen; Thomas Weyhermüller; Markus Hölscher; Christophe Werlé; Walter Leitner
Journal:  Nat Commun       Date:  2018-10-30       Impact factor: 14.919
View more

北京卡尤迪生物科技股份有限公司 © 2022-2023.