Literature DB >> 20536207

Stereocontrolled synthesis of trans-cyclopropyl sulfones from terminal epoxides.

Christopher D Bray1, Giorgio de Faveri.   

Abstract

Treatment of a range of (enantiopure) epoxides with the sodium salt of diethyl (phenylsulfonyl)methylphosphonate in DME at 140 degrees C for 4 h gives a variety of (enantiopure) trans-cyclopropyl sulfones with high diastereoselectivity.

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Year:  2010        PMID： 20536207     DOI： 10.1021/jo100844g

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  3 in total

1.  Validation of diethoxyphosphonate as an effective agent for charge transfer in Anion Relay Chemistry (ARC).

Authors:  Alexander Sokolsky; Amos B Smith
Journal:  Org Lett       Date:  2012-08-10       Impact factor: 6.005

2.  Sultones and Sultines via a Julia-Kocienski Reaction of Epoxides.

Authors:  Geoffrey M T Smith; Paul M Burton; Christopher D Bray
Journal:  Angew Chem Int Ed Engl       Date:  2015-10-27       Impact factor: 15.336

3.  Divergent Synthesis of Cyclopropane-Containing Lead-Like Compounds, Fragments and Building Blocks through a Cobalt Catalyzed Cyclopropanation of Phenyl Vinyl Sulfide.

Authors:  Stephen J Chawner; Manuel J Cases-Thomas; James A Bull
Journal:  European J Org Chem       Date:  2017-09-11
  3 in total

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