Literature DB >> 20527926

Polymeric ethyl glyoxylate in an asymmetric aldol reaction catalyzed by diarylprolinol.

Tatsuya Urushima1, Yusuke Yasui, Hayato Ishikawa, Yujiro Hayashi.   

Abstract

Diarylprolinol was found to be an effective organocatalyst of the direct, enantioselective aldol reaction of commercially available polymeric ethyl glyoxylate, affording gamma-ethoxycarbonyl-beta-hydroxy aldehydes, versatile synthetic intermediates, in good yield with excellent enantioselectivity.

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Year:  2010        PMID： 20527926     DOI： 10.1021/ol1009812

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

1.  Developing novel organocatalyzed aldol reactions for the enantioselective synthesis of biologically active molecules.

Authors:  Mayur Bhanushali; Cong-Gui Zhao
Journal:  Synthesis (Stuttg)       Date:  2011-06       Impact factor: 3.157

2.  Organocatalyzed enantioselective aldol reaction of 1H-pyrrole-2,3-diones.

Authors:  Mayur Bhanushali; Cong-Gui Zhao
Journal:  Tetrahedron Lett       Date:  2011-11-19       Impact factor: 2.415

3.  The Cyclohexa-2,5-dienyl Group as a Placeholder for Hydrogen: Organocatalytic Michael Addition of an Acetaldehyde Surrogate.

Authors:  Weiqiang Chen; Huaquan Fang; Kaixue Xie; Martin Oestreich
Journal:  Chemistry       Date:  2020-10-22       Impact factor: 5.236
  3 in total

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