Literature DB >> 20527724

Elusive ethynyl azides: trapping by 1,3-dipolar cycloaddition and decomposition to cyanocarbenes.

Klaus Banert1, Manfred Hagedorn, Jens Wutke, Petra Ecorchard, Dieter Schaarschmidt, Heinrich Lang.   

Abstract

Although they decompose rapidly to produce cyanocarbenes, ethynyl azides were generated from (chloroethynyl)arenes and trapped for the first time by 1,3-dipolar cycloaddition at cyclooctyne.

Entities:  

Year:  2010        PMID： 20527724     DOI： 10.1039/c0cc00079e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Synthesis of hypervalent iodonium alkynyl triflates for the application of generating cyanocarbenes.

Authors:  I F Dempsey Hyatt; Daniel J Nasrallah; Mitchell P Croatt
Journal:  J Vis Exp       Date:  2013-09-08       Impact factor: 1.355

2.  Copper-catalyzed direct transformation of simple alkynes to alkenyl nitriles via aerobic oxidative N-incorporation.

Authors:  Xiaoqiang Huang; Xinyao Li; Ning Jiao
Journal:  Chem Sci       Date:  2015-07-20       Impact factor: 9.825

3.  Synthesis of New 2-Halo-2-(1H-tetrazol-5-yl)-2H-azirines via a Non-Classical Wittig Reaction.

Authors:  Ana L Cardoso; Carmo Sousa; Marta S C Henriques; José A Paixão; Teresa M V D Pinho e Melo
Journal:  Molecules       Date:  2015-12-12       Impact factor: 4.411
  3 in total

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