Literature DB >> 20520891

Stoichiometric and catalytic Sn-mediated dehydrocoupling of primary phosphines.

Vesal Naseri1, Robert J Less, Robert E Mulvey, Mary McPartlin, Dominic S Wright.   

Abstract

The room-temperature reactions of stannocene, Cp*(2)Sn, with a range of primary phosphines, RPH(2), result in diphosphanes [RP(H)P(H)R]. The reactions involving Cp*(2)SnCl(2), however, result in catalytic dehydrocoupling; the first example of main group metal catalysed dehydrocoupling to be identified.

Entities:  

Year:  2010        PMID： 20520891     DOI： 10.1039/c0cc00827c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

Review 1.  Catalysis in service of main group chemistry offers a versatile approach to p-block molecules and materials.

Authors:  Erin M Leitao; Titel Jurca; Ian Manners
Journal:  Nat Chem       Date:  2013-10       Impact factor: 24.427

2.  Exploiting the Brønsted acidity of phosphinecarboxamides for the synthesis of new phosphides and phosphines.

Authors:  Andrew R Jupp; Gemma Trott; Éléonore Payen de la Garanderie; James D G Holl; Duncan Carmichael; Jose M Goicoechea
Journal:  Chemistry       Date:  2015-04-17       Impact factor: 5.236

3.  Homo- and heterodehydrocoupling of phosphines mediated by alkali metal catalysts.

Authors:  Lipeng Wu; Vincent T Annibale; Haijun Jiao; Adam Brookfield; David Collison; Ian Manners
Journal:  Nat Commun       Date:  2019-06-26       Impact factor: 14.919

4.  Steric Effects Dictate the Formation of Terminal Arylborylene Complexes of Ruthenium from Dihydroboranes.

Authors:  Carsten Lenczyk; Dipak Kumar Roy; Jörn Nitsch; Krzysztof Radacki; Florian Rauch; Rian D Dewhurst; F Matthias Bickelhaupt; Todd B Marder; Holger Braunschweig
Journal:  Chemistry       Date:  2019-09-17       Impact factor: 5.236
  4 in total

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