| Literature DB >> 20508887 |
Frederick G Baddour1, Michael I Kahn, James A Golen, Arnold L Rheingold, Linda H Doerrer.
Abstract
Herein we report the first structural characterization of a Pt(iv)-kappa(3)-terpyridine species, [Pt((t)Bu(3)tpy)Cl(3)][AuCl(2)], which can be prepared by oxidation with [AuCl(4)](-). The syntheses and characterization of [Pt((t)Bu(3)tpy)Cl(3)]Cl ((t)Bu(3)tpy is 4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine), as well as the platinum(ii) complexes [Pt((t)Bu(3)tpy)Cl]Cl and [Pt((t)Bu(3)tpy)Cl][AuCl(2)] are reported.Entities:
Year: 2010 PMID： 20508887 DOI： 10.1039/c0cc00283f
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222