Literature DB >> 20508879

Dehydrogenation of ammonia-borane by Shvo's catalyst.

Brian L Conley1, Travis J Williams.   

Abstract

Shvo's cyclopentadienone-ligated ruthenium complex is an efficient catalyst for the liberation of exactly two molar equivalents of hydrogen from ammonia-borane, a prospective hydrogen storage medium. The mechanism for the dehydrogenation features a ruthenium hydride resting state from which dihydrogen loss is the rate-determining step.

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Year:  2010        PMID： 20508879     DOI： 10.1039/c003157g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

1.  Dehydrogenation of ammonia borane through the third equivalent of hydrogen.

Authors:  Xingyue Zhang; Lisa Kam; Travis J Williams
Journal:  Dalton Trans       Date:  2016-05-04       Impact factor: 4.390

2.  A robust, air-stable, reusable ruthenium catalyst for dehydrogenation of ammonia borane.

Authors:  Brian L Conley; Denver Guess; Travis J Williams
Journal:  J Am Chem Soc       Date:  2011-08-18       Impact factor: 15.419

3.  Synthesis of Ruthenium Boryl Analogues of the Shvo Metal-Ligand Bifunctional Catalyst.

Authors:  Liza Koren-Selfridge; Ian P Query; Joel A Hanson; Nicholas A Isley; Ilia A Guzei; Timothy B Clark
Journal:  Organometallics       Date:  2010       Impact factor: 3.876

4.  A Three-Stage Mechanistic Model for Ammonia Borane Dehydrogenation by Shvo's Catalyst.

Authors:  Zhiyao Lu; Brian L Conley; Travis J Williams
Journal:  Organometallics       Date:  2012-08-30       Impact factor: 3.876

5.  Probing the second dehydrogenation step in ammonia-borane dehydrocoupling: characterization and reactivity of the key intermediate, B-(cyclotriborazanyl)amine-borane.

Authors:  Hassan A Kalviri; Felix Gärtner; Gang Ye; Ilia Korobkov; R Tom Baker
Journal:  Chem Sci       Date:  2014-10-30       Impact factor: 9.825

6.  Molybdenum catalyzed ammonia borane dehydrogenation: oxidation state specific mechanisms.

Authors:  Joshua A Buss; Guy A Edouard; Christine Cheng; Jade Shi; Theodor Agapie
Journal:  J Am Chem Soc       Date:  2014-07-30       Impact factor: 15.419
  6 in total

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