| Literature DB >> 20507079 |
Qing-Long Xu1, Wen-Bo Liu, Li-Xin Dai, Shu-Li You.
Abstract
With an [Ir(COD)Cl](2)/phosphoramidite ligand system, an allylic substitution of O-allyl carbamothioates was developed. The reaction proceeded in the favor of branched products with up to 93:7 branched-to-linear ratio, affording chiral S-allyl carbamothioates with up to 95% ee.Entities:
Year: 2010 PMID： 20507079 DOI： 10.1021/jo1006152
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354