Literature DB >> 20502820

The first asymmetric organolithium tetramers with simple ether donor bases.

Tanja Tatic1, Kathrin Meindl, Julian Henn, Sushil Kumar Pandey, Dietmar Stalke.   

Abstract

The donor-free trimethylsilylmethyllithium [LiCH(2)SiMe(3)](6) hexameric aggregate is for the first time broken up by simple ether donors such as diethyl ether (Et(2)O) and tert-butylmethyl ether ((t)BuOMe) to give the unprecedented asymmetric tetramers while the chelating dimethoxyethane (DME) gives the expected dimer.

Entities:  

Year:  2010        PMID: 20502820     DOI: 10.1039/c002504f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

Review 1.  200 Years of Lithium and 100 Years of Organolithium Chemistry.

Authors:  Ulrich Wietelmann; Jan Klett
Journal:  Z Anorg Allg Chem       Date:  2018-01-17       Impact factor: 1.492

2.  Solvation Effects on the Structure and Stability of Alkali Metal Carbenoids.

Authors:  Katharina Dilchert; Michelle Schmidt; Angela Großjohann; Kai-Stephan Feichtner; Robert E Mulvey; Viktoria H Gessner
Journal:  Angew Chem Int Ed Engl       Date:  2020-11-03       Impact factor: 15.336

  2 in total

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