| Literature DB >> 20491439 |
Moushumi Sarma1, Apurba Kalita, Pankaj Kumar, Amardeep Singh, Biplab Mondal.
Abstract
The copper(II) centers in two copper(II) complexes of tripodal amine ligands, in acetonitrile solvent, upon exposure to nitric oxide have been found to produce a thermally unstable [Cu(II)-NO] intermediate followed by the reduction of copper(II) to copper(I). This reduction resulted in the concomitant trinitrosation of the ligands at their terminal amine centers.Entities:
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Year: 2010 PMID： 20491439 DOI： 10.1021/ja102279c
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419