Literature DB >> 20490404

Unusual magnetic properties of a two-coordinate heteroleptic linear cobalt(II) complex.

Chengbao Ni1, Troy A Stich, Gary J Long, Philip P Power.   

Abstract

The synthesis and characterization of two-coordinate cobalt(ii) complexes CoAr'(2) (1) and Ar'CoN(SiMe(3))(2) (2) (Ar' = C(6)H(3)-2,6-(C(6)H(3)-2,6-(i)Pr(2))(2)) are reported. The magnetic data for 2 show that it has an unexpectedly high mu(eff) of 5.65 mu(B) whereas the bent complex 1 has a significantly lower moment.

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Year:  2010        PMID: 20490404     DOI: 10.1039/c001483d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Observation of the single-ion magnet behavior of d8 ions on two-coordinate Co(i)-NHC complexes.

Authors:  Yin-Shan Meng; Zhenbo Mo; Bing-Wu Wang; Yi-Quan Zhang; Liang Deng; Song Gao
Journal:  Chem Sci       Date:  2015-09-10       Impact factor: 9.825

  1 in total

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