Literature DB >> 20481528

CuH-catalyzed enantioselective 1,2-reductions of alpha,beta-unsaturated ketones.

Ralph Moser1, Zarko V Bosković, Christopher S Crowe, Bruce H Lipshutz.   

Abstract

The first study on a general technology for arriving at valued nonracemic allylic alcohols using asymmetric ligand-accelerated catalysis by copper hydride is described.

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Year:  2010        PMID： 20481528      PMCID： PMC3365512          DOI： 10.1021/ja102689e

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  14 in total

1.  Ligand-accelerated, copper-catalyzed asymmetric hydrosilylations of aryl ketones.

Authors:  B H Lipshutz; K Noson; W Chrisman
Journal:  J Am Chem Soc       Date:  2001-12-26       Impact factor: 15.419

2.  Copper(I) hydride-catalyzed asymmetric hydrosilylation of heteroaromatic ketones.

Authors:  Bruce H Lipshutz; Asher Lower; Kevin Noson
Journal:  Org Lett       Date:  2002-11-14       Impact factor: 6.005

3.  Catalytic enantioselective conjugate reduction of beta,beta-disubstituted nitroalkenes.

Authors:  Constantin Czekelius; Erick M Carreira
Journal:  Angew Chem Int Ed Engl       Date:  2003-10-13       Impact factor: 15.336

4.  Highly enantioselective conjugate reduction of beta,beta-disubstituted alpha,beta-unsaturated nitriles.

Authors:  Daehyung Lee; Daesung Kim; Jaesook Yun
Journal:  Angew Chem Int Ed Engl       Date:  2006-04-21       Impact factor: 15.336

Review 5.  CuH-catalyzed reactions.

Authors:  Carl Deutsch; Norbert Krause
Journal:  Chem Rev       Date:  2008-07-11       Impact factor: 60.622

6.  Copper-catalyzed enantioselective hydrosilylation of ketones by using monodentate binaphthophosphepine ligands.

Authors:  Kathrin Junge; Bianca Wendt; Daniele Addis; Shaolin Zhou; Shoubhik Das; Matthias Beller
Journal:  Chemistry       Date:  2010-01-04       Impact factor: 5.236

7.  Tandem nucleophilic addition/fragmentation reactions and synthetic versatility of vinylogous acyl triflates.

Authors:  Shin Kamijo; Gregory B Dudley
Journal:  J Am Chem Soc       Date:  2006-05-17       Impact factor: 15.419

8.  High performance of Rh(Phebox) catalysts in asymmetric reductive aldol reaction: high anti-selectivity.

Authors:  Hisao Nishiyama; Takushi Shiomi; Yasunori Tsuchiya; Isamu Matsuda
Journal:  J Am Chem Soc       Date:  2005-05-18       Impact factor: 15.419

9.  Catalytic enantioselective conjugate reduction of lactones and lactams.

Authors:  Gregory Hughes; Masanari Kimura; Stephen L Buchwald
Journal:  J Am Chem Soc       Date:  2003-09-17       Impact factor: 15.419

10.  Asymmetric 1,4-hydrosilylations of alpha,beta-unsaturated esters.

Authors:  Bruce H Lipshutz; Jeff M Servesko; Benjamin R Taft
Journal:  J Am Chem Soc       Date:  2004-07-14       Impact factor: 15.419
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  8 in total

1.  CuH-Catalyzed Asymmetric Reduction of α,β-Unsaturated Carboxylic Acids to β-Chiral Aldehydes.

Authors:  Yujing Zhou; Jeffrey S Bandar; Richard Y Liu; Stephen L Buchwald
Journal:  J Am Chem Soc       Date:  2018-01-04       Impact factor: 15.419

2.  Confronting the Challenging Asymmetric Carbonyl 1,2-Addition Using Vinyl Heteroarene Pronucleophiles: Ligand-Controlled Regiodivergent Processes through a Dearomatized Allyl-Cu Species.

Authors:  Yuyang Dong; Alexander W Schuppe; Binh Khanh Mai; Peng Liu; Stephen L Buchwald
Journal:  J Am Chem Soc       Date:  2022-03-26       Impact factor: 16.383

3.  A Regio- and Enantioselective CuH-Catalyzed Ketone Allylation with Terminal Allenes.

Authors:  Erica Y Tsai; Richard Y Liu; Yang Yang; Stephen L Buchwald
Journal:  J Am Chem Soc       Date:  2018-02-02       Impact factor: 15.419

4.  The hydrogenase activity of the molybdenum/copper-containing carbon monoxide dehydrogenase of Oligotropha carboxidovorans.

Authors:  Jarett Wilcoxen; Russ Hille
Journal:  J Biol Chem       Date:  2013-10-28       Impact factor: 5.157

5.  Copper-catalysed enantioselective stereodivergent synthesis of amino alcohols.

Authors:  Shi-Liang Shi; Zackary L Wong; Stephen L Buchwald
Journal:  Nature       Date:  2016-03-28       Impact factor: 49.962

6.  Atomically Precise, Thiolated Copper-Hydride Nanoclusters as Single-Site Hydrogenation Catalysts for Ketones in Mild Conditions.

Authors:  Cunfa Sun; Nisha Mammen; Sami Kaappa; Peng Yuan; Guocheng Deng; Chaowei Zhao; Juanzhu Yan; Sami Malola; Karoliina Honkala; Hannu Häkkinen; Boon K Teo; Nanfeng Zheng
Journal:  ACS Nano       Date:  2019-05-10       Impact factor: 15.881

7.  Copper(i) pyrimidine-2-thiolate cluster-based polymers as bifunctional visible-light-photocatalysts for chemoselective transfer hydrogenation of α,β-unsaturated carbonyls.

Authors:  Meng Juan Zhang; David James Young; Ji Long Ma; Guo Quan Shao
Journal:  RSC Adv       Date:  2021-04-21       Impact factor: 3.361

8.  Ir/f-Ampha complex catalyzed asymmetric sequential hydrogenation of enones: a general access to chiral alcohols with two contiguous chiral centers.

Authors:  Wendian Li; Tilong Yang; Nan Song; Ruihao Li; Jiao Long; Lin He; Xumu Zhang; Hui Lv
Journal:  Chem Sci       Date:  2022-01-18       Impact factor: 9.825
  8 in total

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