Literature DB >> 20481483

Total synthesis of 7,11-cyclobotryococca-5,12,26-triene using an oxidative radical cyclization as a key step.

Justin J Davies1, Thomas M Krulle, Jonathan W Burton.   

Abstract

An efficient total synthesis of the novel botryococcene-related hydrocarbon 7,11-cyclobotryococca-5,12,26-triene is reported that uses, as a key step, an oxidative radical cyclization of a 4-pentenyl malonate for the synthesis of a [3.3.0]-bicyclic gamma-lactone.

Entities:  

Year:  2010        PMID： 20481483     DOI： 10.1021/ol100794k

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  5 in total

1.  Nature-inspired total synthesis of (-)-fusarisetin A.

Authors:  Jing Xu; Eduardo J E Caro-Diaz; Lynnie Trzoss; Emmanuel A Theodorakis
Journal:  J Am Chem Soc       Date:  2012-03-08       Impact factor: 15.419

2.  A Short Synthesis of Aphanamol I in Both Racemic and Enantiopure Forms.

Authors:  Steven J Ferrara; Jonathan W Burton
Journal:  Chemistry       Date:  2016-07-08       Impact factor: 5.236

3.  Cross-Metathesis of Methallyl Halides: Concise Enantioselective Formal Total Synthesis of (-)-Presphaerene.

Authors:  Suresh Mandava; Jaun Koo; Jungjoong Hwang; Hari Krishna Nallapaneni; Haeil Park; Jongkook Lee
Journal:  Front Chem       Date:  2020-06-30       Impact factor: 5.221

4.  Synthetic Routes to Methylerythritol Phosphate Pathway Intermediates and Downstream Isoprenoids.

Authors:  Sarah K Jarchow-Choy; Andrew T Koppisch; David T Fox
Journal:  Curr Org Chem       Date:  2014-04       Impact factor: 2.180

5.  Manganese(III) acetate-mediated oxidative cyclization of a-methylstyrene and trans-stilbene with b-ketosulfones.

Authors:  Ahlem Bouhlel; Christophe Curti; Clémence Tabelé; Patrice Vanelle
Journal:  Molecules       Date:  2013-04-11       Impact factor: 4.411
  5 in total

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