| Literature DB >> 20465292 |
Alan Armstrong1, Robert D C Pullin, Chloe R Jenner, James N Scutt.
Abstract
N-Unsubstituted vinyl aziridines were synthesized via an amine-promoted regioselective nucleophilic aziridination of alpha,beta,gamma,delta-unsaturated carbonyl compounds. The reaction is completely regioselective (>95: 5) for the alpha,beta-alkene and completely diastereoselective, affording the trans-vinyl aziridine in moderate-to-good yields.Entities:
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Year: 2010 PMID： 20465292 DOI： 10.1021/jo100407s
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354