Literature DB >> 20464006

A scandium terminal imido complex: synthesis, structure and DFT studies.

Erli Lu1, Yuxue Li, Yaofeng Chen.   

Abstract

The first rare earth metal terminal imido complex has been isolated and structurally characterized. The complex has an extremely short M-N bond length and a nearly linear M-N-C angle. DFT studies showed two p orbitals of N(imido) atom form two bonds with two d orbitals of rare earth metal ion.

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Year:  2010        PMID: 20464006     DOI: 10.1039/c002870c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Carbenes and alkylidenes: Spot the difference.

Authors:  Daniel J Mindiola; Jennifer Scott
Journal:  Nat Chem       Date:  2011-01       Impact factor: 24.427

  1 in total

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