Literature DB >> 20455551

Angularly fused triquinanes from linear substrates through trimethylenemethane diyl [2 + 3] cycloaddition reaction.

Hee-Yoon Lee1, Yongsik Jung, Yeokwon Yoon, Byung Gyu Kim, Yeonjoon Kim.   

Abstract

Angularly fused triquinanes were synthesized from linear dienes and phenyl(propynyl)iodonium salt through trimethylenemethane (TMM) diyl mediated [2 + 3] cycloaddition reaction. TMM diyl intermediates were obtained from alkylidene carbenes generated from reactions of alkynyliodonium salts with nucleophiles.

Entities:  

Year:  2010        PMID: 20455551     DOI: 10.1021/ol100907t

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

1.  Synthesis of hypervalent iodonium alkynyl triflates for the application of generating cyanocarbenes.

Authors:  I F Dempsey Hyatt; Daniel J Nasrallah; Mitchell P Croatt
Journal:  J Vis Exp       Date:  2013-09-08       Impact factor: 1.355

  1 in total

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