| Literature DB >> 20452674 |
Timo A Immel1, Josefine T Martin, Christoph J Dürr, Ulrich Groth, Thomas Huhn.
Abstract
Reaction of the known titanocene Y 2 with methyl lithium at -15 degrees C yields bis-[(p-methoxybenzyl)cyclopentadienyl]titanium(IV) dimethyl (dimethyl titanocene Y, 3), a hitherto unknown, surprisingly robust titanium (IV) dimethyl species. Dimethyl titanocene Y was utilized in the preparation of several bis-[(p-methoxybenzyl)cyclopentadienyl]titanium(IV) dicarboxylates by the reaction with the free carboxylic acids in fair to good yields. Cytotoxicity of all new compounds has been estimated in Hela S3 cells. (c) 2010 Elsevier Inc. All rights reserved.Entities:
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Year: 2010 PMID： 20452674 DOI： 10.1016/j.jinorgbio.2010.04.003
Source DB: PubMed Journal: J Inorg Biochem ISSN： 0162-0134 Impact factor: 4.155