Literature DB >> 20450167

High yield C-derivatization of weakly coordinating carborane anions.

Matthew J Nava1, Christopher A Reed.   

Abstract

Unlike the "parent" carborane anion CHB(11)H(11)(-), halogenated carborane anions such as CHB(11)H(5)Br(6)(-) can be readily C-functionalized in high yield and purity, enhancing their utility as weakly coordinating anions.

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Year:  2010        PMID： 20450167      PMCID： PMC2883884          DOI： 10.1021/ic100053u

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  11 in total

1.  Molecular Rods. 1. Simple Axial Rods.

Authors:  Peter F. H. Schwab; Michael D. Levin; Josef Michl
Journal:  Chem Rev       Date:  1999-07-14       Impact factor: 60.622

2.  Noncoordinating anions--fact or fiction? A survey of likely candidates.

Authors:  Ingo Krossing; Ines Raabe
Journal:  Angew Chem Int Ed Engl       Date:  2004-04-13       Impact factor: 15.336

3.  Salts of the 1-cyanocarba-closo-dodecaborate anions [1-NC-closo-1-CB11X11]- (X = H, F, Cl, Br, I).

Authors:  Maik Finze; Jan A P Sprenger; Bernd Bastian Schaack
Journal:  Dalton Trans       Date:  2010-02-04       Impact factor: 4.390

4.  [Me3Si][R-CB11F11]--synthesis and properties.

Authors:  Torsten Küppers; Eduard Bernhardt; Reint Eujen; Helge Willner; Christian W Lehmann
Journal:  Angew Chem Int Ed Engl       Date:  2007       Impact factor: 15.336

5.  H(+), CH(3)(+), and R(3)Si(+) carborane reagents: when triflates fail.

Authors:  Christopher A Reed
Journal:  Acc Chem Res       Date:  2010-01-19       Impact factor: 22.384

6.  Highly Chlorinated, Brominated, and Iodinated Icosahedral Carborane Anions: 1-H-CB(11)X(11)(-), 1-CH(3)-CB(11)X(11)(-) (X = Cl, Br, I); 1-Br-CB(11)Br(11)(-).

Authors:  Zuowei Xie; Chi-Wing Tsang; Eric Tung-Po Sze; Qingchuan Yang; Dominic T. W. Chan; Thomas C. W. Mak
Journal:  Inorg Chem       Date:  1998-12-14       Impact factor: 5.165

7.  Chemistry of the carba-closo-dodecaborate(-) anion, CB(11)H(12)(-).

Authors:  Stefanie Körbe; Peter J Schreiber; Josef Michl
Journal:  Chem Rev       Date:  2006-12       Impact factor: 60.622

8.  The sixteen CB(11)H(n)Me(12-n)(-) anions with fivefold substitution symmetry: anodic oxidation and electronic structure.

Authors:  Benjamin T King; Stefanie Körbe; Peter J Schreiber; Joshua Clayton; Adriana Nemcova; Zdenek Havlas; Kamesh Vyakaranam; Matthew G Fete; Ilya Zharov; Jason Ceremuga; Josef Michl
Journal:  J Am Chem Soc       Date:  2007-10-05       Impact factor: 15.419

9.  Gas-phase Brønsted superacidity of some derivatives of monocarba-closo-borates: a computational study.

Authors:  Lauri Lipping; Ivo Leito; Ivar Koppel; Ilmar A Koppel
Journal:  J Phys Chem A       Date:  2009-11-19       Impact factor: 2.781

10.  A copolymerized dodecacarborane anion as covalently attached cation exchanger in ion-selective sensors.

Authors:  Yu Qin; Eric Bakker
Journal:  Anal Chem       Date:  2003-11-01       Impact factor: 6.986
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