Literature DB >> 20449525

Remarkable effect of phosphine on the reactivity of O,P-acetal--efficient substitution reaction of O,P-acetal.

Hiromichi Fujioka1, Akihiro Goto, Kazuki Otake, Ozora Kubo, Kenzo Yahata, Yoshinari Sawama, Tomohiro Maegawa.   

Abstract

The structure and electronic nature of the phosphine have a significant influence on not only the formation, but also the subsequent transformation of O,P-acetals. The O,P-acetals generated from tris(o-tolyl)phosphine [(o-tol)(3)P] underwent efficient substitution reactions with various nucleophiles.

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Year:  2010        PMID: 20449525     DOI: 10.1039/c0cc00170h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Facile synthesis of α-alkoxymethyltriphenylphosphonium iodides: new application of PPh3/I2.

Authors:  Humaira Yasmeen Gondal; Zain Maqsood Cheema; Javid Hussain Zaidi; Sammer Yousuf; M Iqbal Choudhary
Journal:  Chem Cent J       Date:  2018-05-17       Impact factor: 4.215

  1 in total

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