Literature DB >> 20449444

A synthetic model of Hg(II) sequestration.

Julie A Viehweg1, Sarah M Stamps, Jennifer J Dertinger, Robert L Green, Katherine E Harris, Raymond J Butcher, Erica J Andriole, J C Poutsma, Steven M Berry, Deborah C Bebout.   

Abstract

Tridentate ligand N-(2-pyridylmethyl)-N-(2-(ethylthiolato)amine (L) forms the novel complex [Hg(5)(L)(6)](ClO(4))(4).toluene () with a bicyclo[3.3.3] Hg(5)S(6) core and 4-, 5- and 6-coordinate metal centers; characterization of a solution of by ESI-MS revealed elaborate speciation involving [Hg(n)L(n+1)(ClO(4))(n-2)](+), [Hg(n)L(n)(ClO(4))(n-1)](+) and [Hg(n)L(n-1)(ClO(4))(n)](+) ion families.

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Year:  2010        PMID: 20449444     DOI: 10.1039/c000002g

Source DB:  PubMed          Journal:  Dalton Trans        ISSN: 1477-9226            Impact factor:   4.390


  1 in total

1.  Carbonate-templated self-assembly of an alkylthiolate-bridged cadmium macrocycle.

Authors:  Wei Lai; Steven M Berry; William P Kaplan; Malia S Hain; John C Poutsma; Raymond J Butcher; Robert D Pike; Deborah C Bebout
Journal:  Inorg Chem       Date:  2013-02-13       Impact factor: 5.165

  1 in total

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