| Literature DB >> 20449444 |
Julie A Viehweg1, Sarah M Stamps, Jennifer J Dertinger, Robert L Green, Katherine E Harris, Raymond J Butcher, Erica J Andriole, J C Poutsma, Steven M Berry, Deborah C Bebout.
Abstract
Tridentate ligand N-(2-pyridylmethyl)-N-(2-(ethylthiolato)amine (L) forms the novel complex [Hg(5)(L)(6)](ClO(4))(4).toluene () with a bicyclo[3.3.3] Hg(5)S(6) core and 4-, 5- and 6-coordinate metal centers; characterization of a solution of by ESI-MS revealed elaborate speciation involving [Hg(n)L(n+1)(ClO(4))(n-2)](+), [Hg(n)L(n)(ClO(4))(n-1)](+) and [Hg(n)L(n-1)(ClO(4))(n)](+) ion families.Mesh:
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Year: 2010 PMID: 20449444 DOI: 10.1039/c000002g
Source DB: PubMed Journal: Dalton Trans ISSN: 1477-9226 Impact factor: 4.390