Literature DB >> 20449331

Friedel-Crafts alkylation of arenes with epoxides promoted by fluorinated alcohols or water.

Guo-Xing Li1, Jin Qu.   

Abstract

The stereoselective intra- and intermolecular Friedel-Crafts alkylation of electron-rich arenes with epoxides can take place in refluxing 1,1,1,3,3,3-hexafluoroisopropanol owing to its weak acidity and high ionizing power.

Entities:  

Year:  2010        PMID： 20449331     DOI： 10.1039/b926684d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  9 in total

1.  Synthesis of a tetrasubstituted tetrahydronaphthalene scaffold for α-helix mimicry via a MgBr2-catalyzed Friedel-Crafts epoxide cycloalkylation.

Authors:  Devan Naduthambi; Santosh Bhor; Michael B Elbaum; Neal J Zondlo
Journal:  Org Lett       Date:  2013-09-09       Impact factor: 6.005

2.  Ni/Photoredox-Catalyzed Enantioselective Cross-Electrophile Coupling of Styrene Oxides with Aryl Iodides.

Authors:  Sii Hong Lau; Meredith A Borden; Talia J Steiman; Lucy S Wang; Marvin Parasram; Abigail G Doyle
Journal:  J Am Chem Soc       Date:  2021-09-20       Impact factor: 15.419

3.  Asymmetric synthesis of flavanols via Cu-catalyzed kinetic resolution of chromenes and their anti-inflammatory activity.

Authors:  Qingjing Yang; Zihao Wang; Catherine Hong Huan Hor; Haitao Xiao; Zhaoxiang Bian; Jun Joelle Wang
Journal:  Sci Adv       Date:  2022-06-03       Impact factor: 14.957

4.  Friedel-Crafts alkylation reaction with fluorinated alcohols as hydrogen-bond donors and solvents.

Authors:  Ren-Jin Tang; Thierry Milcent; Benoit Crousse
Journal:  RSC Adv       Date:  2018-03-13       Impact factor: 4.036

5.  cis-Diastereoselective synthesis of chroman-fused tetralins as B-ring-modified analogues of brazilin.

Authors:  Dimpee Gogoi; Runjun Devi; Pallab Pahari; Bipul Sarma; Sajal Kumar Das
Journal:  Beilstein J Org Chem       Date:  2016-12-21       Impact factor: 2.883

6.  Fe(OTf)3-catalysed Friedel-Crafts reaction of benzenoid arenes with α,β-unsaturated carbonyl compounds: easy access to 1,1-diarylalkanes.

Authors:  Aditya Bhattacharya; Pushpendra Mani Shukla; Biswajit Maji
Journal:  R Soc Open Sci       Date:  2017-10-25       Impact factor: 2.963

Review 7.  Synthetically important ring opening reactions by alkoxybenzenes and alkoxynaphthalenes.

Authors:  Ranadeep Talukdar
Journal:  RSC Adv       Date:  2020-08-25       Impact factor: 4.036

8.  Improved synthesis of structural analogues of (-)-epicatechin gallate for modulation of staphylococcal β-lactam resistance.

Authors:  James C Anderson; Helen Grounds; Suzanna Reeves; Peter W Taylor
Journal:  Tetrahedron       Date:  2014-05-27       Impact factor: 2.457

9.  HFIP-Promoted Synthesis of Substituted Tetrahydrofurans by Reaction of Epoxides with Electron-Rich Alkenes.

Authors:  Natalia Llopis; Alejandro Baeza
Journal:  Molecules       Date:  2020-07-30       Impact factor: 4.411
  9 in total

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