| Literature DB >> 20449267 |
Erika R Bartholomew1, Steven H Bertz, Stephen K Cope, Michael D Murphy, Craig A Ogle, Andy A Thomas.
Abstract
Lithium tetramethylcuprate(III), Me(4)CuLi, the Cu(III) analog of the Gilman reagent, has been prepared in high yield from halo-Gilman reagents Me(2)CuLi.LiX (X = Cl, Br, I) and 2,3-dichloropropene and found to have surprising thermal stability. The cyano-Gilman reagent (X = CN) follows a different pathway.Entities:
Year: 2010 PMID： 20449267 DOI： 10.1039/b924000d
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222