Literature DB >> 20448972

Direct catalytic asymmetric aldol reaction of beta-keto esters with formaldehyde promoted by a dinuclear Ni2-Schiff base complex.

Shinsuke Mouri1, Zhihua Chen, Shigeki Matsunaga, Masakatsu Shibasaki.   

Abstract

A homodinuclear Ni(2)-Schiff base 1 complex (0.1-1 mol%) promoted the direct catalytic asymmetric aldol reaction of beta-keto esters with formaldehyde, giving hydroxymethylated adducts in 94-66% ee.

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Year:  2009        PMID： 20448972     DOI： 10.1039/b912380f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  7 in total

Review 1.  The direct catalytic asymmetric aldol reaction.

Authors:  Barry M Trost; Cheyenne S Brindle
Journal:  Chem Soc Rev       Date:  2010-02-17       Impact factor: 54.564

2.  Hydroxymethylation beyond Carbonylation: Enantioselective Iridium-Catalyzed Reductive Coupling of Formaldehyde with Allylic Acetates via Enantiotopic π-Facial Discrimination.

Authors:  Victoria J Garza; Michael J Krische
Journal:  J Am Chem Soc       Date:  2016-03-09       Impact factor: 15.419

3.  tert-Butyl 2-methyl-2-(4-nitro-benzo-yl)propanoate.

Authors:  Chelsey M Crosse; Marshall W Logue; Rudy L Luck; Louis R Pignotti; Melissa F Waineo
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-01-30

4.  tert-Butyl 2-(4-chloro-benzo-yl)-2-methyl-propanoate.

Authors:  Chelsey M Crosse; Emily C Kelly; Marshall W Logue; Rudy L Luck; John S Maass; Katlyn C Mehne; Louis R Pignotti
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-01-30

5.  tert-Butyl 2-benzoyl-2-methyl-propanoate.

Authors:  Marshall W Logue; Rudy L Luck; Nicklaus S Maynard; Sandra S Orlowski; Louis R Pignotti; Annie L Putman; Kelli M Whelan
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-01-30

6.  tert-Butyl 2-methyl-2-(4-methyl-benzo-yl)propanoate.

Authors:  Graham B Gould; Brock G Jackman; Marshall W Logue; Rudy L Luck; Louis R Pignotti; Adrian R Smith; Nicholas M White
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-01-30

7.  Catalytic asymmetric 1,4-additions of beta-keto esters to nitroalkenes promoted by a bifunctional homobimetallic Co2-Schiff base complex.

Authors:  Makoto Furutachi; Zhihua Chen; Shigeki Matsunaga; Masakatsu Shibasaki
Journal:  Molecules       Date:  2010-01-22       Impact factor: 4.411
  7 in total

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