| Literature DB >> 20443560 |
Shunichi Fukuzumi1, Hiroaki Kotani, Heather R Lucas, Kaoru Doi, Tomoyoshi Suenobu, Ryan L Peterson, Kenneth D Karlin.
Abstract
A mononuclear Cu(II) complex acts as an efficient catalyst for four-electron reduction of O(2) to H(2)O. Its reduction by a ferrocene derivative (Fc*) and reaction with O(2) leads to the formation of a peroxodicopper(II) complex; this is subsequently reduced by Fc* in the presence of protons to regenerate the Cu(II) complex.Entities:
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Year: 2010 PMID: 20443560 PMCID: PMC2886287 DOI: 10.1021/ja100538x
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419