Literature DB >> 20442884

Four independent structures of a pentacoordinate silicon species at different points on the Berry pseudorotation pathway.

Alan R Bassindale1, M Sohail, Peter G Taylor, Alexander A Korlyukov, Dmitry E Arkhipov.   

Abstract

A new pentacoordinate silicon species containing two chelating ligands has been synthesized. The structures of four independent cations of the same compound correspond to different points on the Berry pseudorotation pathway. The percentage of square planar character varies between 19% and 40%.

Entities:  

Year:  2010        PMID： 20442884     DOI： 10.1039/c000803f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  One-pot Solvothermal Synthesis of Well-ordered Layered Sodium Aluminoalcoholate Complex: A Useful Precursor for the Preparation of Porous Al2O3 Particles.

Authors:  Xiansen Li; Vladimir K Michaelis; Ta-Chung Ong; Stacey J Smith; Ian McKay; Peter Müller; Robert G Griffin; Evelyn N Wang
Journal:  CrystEngComm       Date:  2014-04-14       Impact factor: 3.545

2.  Designed single-step synthesis, structure, and derivative textural properties of well-ordered layered penta-coordinate silicon alcoholate complexes.

Authors:  Xiansen Li; Vladimir K Michaelis; Ta-Chung Ong; Stacey J Smith; Robert G Griffin; Evelyn N Wang
Journal:  Chemistry       Date:  2014-04-15       Impact factor: 5.236
  2 in total

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