Literature DB >> 20438056

Copper-catalyzed remote sp3 C-H chlorination of alkyl hydroperoxides.

Rituparna Kundu1, Zachary T Ball.   

Abstract

A copper-catalyzed methodology to functionalize remote sp(3) C-H bonds in alkyl hydroperoxides is presented. The atom-transfer chlorination utilizes simple ammonium chloride salts as the chlorine source, and the internal redox process requires no external redox reagents.

Entities:  

Year:  2010        PMID： 20438056     DOI： 10.1021/ol100472t

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  14 in total

1.  Ketone-catalyzed photochemical C(sp3)-H chlorination.

Authors:  Lei Han; Jibao Xia; Lin You; Chuo Chen
Journal:  Tetrahedron       Date:  2017-05-04       Impact factor: 2.457

Review 2.  Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/O2 Model Systems to Organometallic Transformations.

Authors:  Rachel Trammell; Khashayar Rajabimoghadam; Isaac Garcia-Bosch
Journal:  Chem Rev       Date:  2019-01-30       Impact factor: 60.622

3.  δ-C-H Mono- and Dihalogenation of Alcohols.

Authors:  Alastair N Herron; Dongxin Liu; Guoqin Xia; Jin-Quan Yu
Journal:  J Am Chem Soc       Date:  2020-01-30       Impact factor: 15.419

4.  Metal-free Regioselective Hydrochlorination of Unactivated Alkenes via a Combined Acid Catalytic System.

Authors:  Shengzong Liang; Gerald B Hammond; Bo Xu
Journal:  Green Chem       Date:  2018-01-02       Impact factor: 10.182

5.  Remote C-H Functionalization via Selective Hydrogen Atom Transfer.

Authors:  Leah M Stateman; Kohki M Nakafuku; David A Nagib
Journal:  Synthesis (Stuttg)       Date:  2018-02-12       Impact factor: 3.157

6.  γ,δ,ε-C(sp(3))-H Functionalization through Directed Radical H-Abstraction.

Authors:  Tao Liu; Tian-Sheng Mei; Jin-Quan Yu
Journal:  J Am Chem Soc       Date:  2015-04-30       Impact factor: 15.419

7.  Site-selective bromination of sp3 C-H bonds.

Authors:  Shyam Sathyamoorthi; Shibdas Banerjee; J Du Bois; Noah Z Burns; Richard N Zare
Journal:  Chem Sci       Date:  2017-11-20       Impact factor: 9.825

8.  Copper(I)-catalysed site-selective C(sp3)-H bond chlorination of ketones, (E)-enones and alkylbenzenes by dichloramine-T.

Authors:  Jianwen Jin; Yichao Zhao; Sara Helen Kyne; Kaveh Farshadfar; Alireza Ariafard; Philip Wai Hong Chan
Journal:  Nat Commun       Date:  2021-07-01       Impact factor: 14.919

9.  Copper-catalyzed aerobic aliphatic C-H oxygenation with hydroperoxides.

Authors:  Pei Chui Too; Ya Lin Tnay; Shunsuke Chiba
Journal:  Beilstein J Org Chem       Date:  2013-06-25       Impact factor: 2.883

Review 10.  C-H bond halogenation catalyzed or mediated by copper: an overview.

Authors:  Wenyan Hao; Yunyun Liu
Journal:  Beilstein J Org Chem       Date:  2015-11-09       Impact factor: 2.883
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