Literature DB >> 20438052

Rh(I)-catalyzed olefin hydroarylation with electron-deficient perfluoroarenes.

Zhong-Ming Sun1, Jing Zhang, Rajith S Manan, Pinjing Zhao.   

Abstract

Assisted by a partially aqueous media, a catalyst system of [Rh(cod)(OH)](2) and DPPBenzene ligand effectively promotes direct conjugate additions by perfluoroarenes. This formal C-H alkylation process represents a rare example of olefin hydroarylation with electron-deficient arenes. The catalyst system can be modified to selectively form the corresponding olefination products under anhydrous conditions.

Entities:  

Year:  2010        PMID： 20438052     DOI： 10.1021/ja102575d

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  6 in total

1.  Methoxy-directed aryl-to-aryl 1,3-rhodium migration.

Authors:  Jing Zhang; Jun-Feng Liu; Angel Ugrinov; Anthony F X Pillai; Zhong-Ming Sun; Pinjing Zhao
Journal:  J Am Chem Soc       Date:  2013-11-07       Impact factor: 15.419

2.  Tuning reactivity and site selectivity of simple arenes in C-H activation: ortho-arylation of anisoles via arene-metal π-complexation.

Authors:  Paolo Ricci; Katrina Krämer; Igor Larrosa
Journal:  J Am Chem Soc       Date:  2014-12-16       Impact factor: 15.419

3.  Metal-free hydroarylation of the side chain carbon-carbon double bond of 5-(2-arylethenyl)-3-aryl-1,2,4-oxadiazoles in triflic acid.

Authors:  Anna S Zalivatskaya; Dmitry S Ryabukhin; Marina V Tarasenko; Alexander Yu Ivanov; Irina A Boyarskaya; Elena V Grinenko; Ludmila V Osetrova; Eugeniy R Kofanov; Aleksander V Vasilyev
Journal:  Beilstein J Org Chem       Date:  2017-05-11       Impact factor: 2.883

4.  Nickel(0)-catalyzed linear-selective hydroarylation of unactivated alkenes and styrenes with aryl boronic acids.

Authors:  Honggui Lv; Li-Jun Xiao; Dongbing Zhao; Qi-Lin Zhou
Journal:  Chem Sci       Date:  2018-07-18       Impact factor: 9.825

5.  Highly regio- and stereoselective phosphinylphosphination of terminal alkynes with tetraphenyldiphosphine monoxide under radical conditions.

Authors:  Dat Phuc Tran; Yuki Sato; Yuki Yamamoto; Shin-Ichi Kawaguchi; Shintaro Kodama; Akihiro Nomoto; Akiya Ogawa
Journal:  Beilstein J Org Chem       Date:  2021-04-20       Impact factor: 2.883

6.  Synthesis and vinyl benzene copolymerization of novel trisubstituted ethylenes: 15. Halogen and methoxy ring-substituted isopropyl 2-cyano-3-phenyl-2-propenoates.

Authors:  Gregory B Kharas; Alessandra Cimino; Sebastian Flieger; Paige M Whelpley; David Ebner; Randi Groy; Christopher R Savittieri; Nita Shinde; Kenneth L Thomas; Sara M Rocus; William S Schjerven
Journal:  Des Monomers Polym       Date:  2020-06-23       Impact factor: 2.650
  6 in total

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