Literature DB >> 20401375

Efficient synthesis of alkyl aryl ketones & ketals via palladium-catalyzed regioselective arylation of vinyl ethers.

Mingcui Liu1, Zeynab Hyder, Yawei Sun, Weijun Tang, Lijin Xu, Jianliang Xiao.   

Abstract

The combination of Pd(OAc)(2) with 1,3-bis(diphenylphosphino)propane (dppp) in ethylene glycol constitutes a high-performance catalytic system for highly regioselective arylation of a range of electron-rich vinyl ethers by aryl bromides to provide, upon hydrolysis, alkyl aryl ketones and cyclic ketals in good yields with up to 3.75 x 10(5) TON and 15625 h(-1) TOF.

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Year:  2010        PMID: 20401375     DOI: 10.1039/c001004a

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN: 1477-0520            Impact factor:   3.876


  2 in total

1.  Cobalt-Catalyzed E-Selective Isomerization of Alkenes with a Phosphine-Amido-Oxazoline Ligand.

Authors:  Hongmei Liu; Cheng Cai; Yanghao Ding; Jianhui Chen; Bosheng Liu; Yuanzhi Xia
Journal:  ACS Omega       Date:  2020-05-12

2.  Palladium-Catalyzed Room Temperature Acylative Cross-Coupling of Activated Amides with Trialkylboranes.

Authors:  Weijia Shi; Gang Zou
Journal:  Molecules       Date:  2018-09-20       Impact factor: 4.411

  2 in total

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