Literature DB >> 20393643

Preparation and characterization of [CF3SO3(SiMe3)2]+[B(C6F5)4]-.

Axel Schulz1, Johannes Thomas, Alexander Villinger.   

Abstract

Using tetrakis(pentafluorophenyl)borate, [B(C(6)F(5))(4)](-), as weakly coordinating counterion, the bis(trimethylsilyl)trifluoromethylsulfonium cation, [CF(3)SO(3)(Me(3)Si)(2)](+), is readily isolated for X-ray, NMR and IR structural characterization.

Entities:  

Year:  2010        PMID： 20393643     DOI： 10.1039/c0cc00013b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Triethylsilyl Perfluoro-Tetraphenylborate, [Et(3)Si][F(20)-BPh(4)], a widely used Non-Existent Compound.

Authors:  Matthew Nava; Christopher A Reed
Journal:  Organometallics       Date:  2011-09-12       Impact factor: 3.876

2.  Isolable fluorinated triphenylmethyl cation salts of [HCB11Cl11]-: demonstration of remarkable hydride affinity.

Authors:  S Olivia Gunther; Chun-I Lee; Ellen Song; Nattamai Bhuvanesh; Oleg V Ozerov
Journal:  Chem Sci       Date:  2022-04-04       Impact factor: 9.969

3.  Reactive p-block cations stabilized by weakly coordinating anions.

Authors:  Tobias A Engesser; Martin R Lichtenthaler; Mario Schleep; Ingo Krossing
Journal:  Chem Soc Rev       Date:  2015-11-27       Impact factor: 54.564
  3 in total

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