Literature DB >> 20390152

Secondary orbital interactions in the propagation steps of lipid peroxidation.

Di Hu1, Derek A Pratt.   

Abstract

Calculations on the propagation steps in the radical chain oxidation of lipids (H-atom abstraction, O(2) addition) show that secondary orbital interactions play an important role in the structure and energetics of the transition states of these reactions.

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Year:  2010        PMID： 20390152     DOI： 10.1039/c0cc00019a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Free radical oxidation of polyunsaturated lipids: New mechanistic insights and the development of peroxyl radical clocks.

Authors:  Derek A Pratt; Keri A Tallman; Ned A Porter
Journal:  Acc Chem Res       Date:  2011-04-12       Impact factor: 22.384

2.  A perspective on free radical autoxidation: the physical organic chemistry of polyunsaturated fatty acid and sterol peroxidation.

Authors:  Ned A Porter
Journal:  J Org Chem       Date:  2013-04-09       Impact factor: 4.354

3.  Lipoxygenase 2 from Cyanothece sp. controls dioxygen insertion by steric shielding and substrate fixation.

Authors:  Julia Newie; Piotr Neumann; Martin Werner; Ricardo A Mata; Ralf Ficner; Ivo Feussner
Journal:  Sci Rep       Date:  2017-05-18       Impact factor: 4.379

4.  The hydrogen atom transfer reactivity of sulfinic acids.

Authors:  Markus Griesser; Jean-Philippe R Chauvin; Derek A Pratt
Journal:  Chem Sci       Date:  2018-07-31       Impact factor: 9.825
  4 in total

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