Literature DB >> 20386853

Photochemical isomerisation of boryl-substituted silole derivatives.

Juri Ugolotti1, Gerald Kehr, Roland Fröhlich, Gerhard Erker.   

Abstract

Bis(alkynyl)silanes (1a,b) react with bis(pentafluorophenyl)-borane to 3-boryl-2,5-bis(trimethylsilyl) substituted siloles 3a,b. Subsequent irradiation of 3 with Pyrex filtered UV light resulted in the complete conversion to the new 5-boryl-2,3-bis(trimethylsilyl) substituted siloles 4a,b.

Entities:  

Year:  2010        PMID: 20386853     DOI: 10.1039/b927221f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Advanced 1,1-carboboration reactions with pentafluorophenylboranes.

Authors:  Gerald Kehr; Gerhard Erker
Journal:  Chem Sci       Date:  2015-10-08       Impact factor: 9.825

  1 in total

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