Literature DB >> 20386828

Isospecific polymerization of racemic epoxides: a catalyst system for the synthesis of highly isotactic polyethers.

Peter C B Widger1, Syud M Ahmed, Wataru Hirahata, Renee M Thomas, Emil B Lobkovsky, Geoffrey W Coates.   

Abstract

A highly active bimetallic cobalt catalyst system is reported for the polymerization of racemic terminal epoxides to yield isotactic polyethers.

Entities:  

Year:  2010        PMID： 20386828     DOI： 10.1039/b926888j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Synthetic Strategy for Preparing Chiral Double-semicrystalline Polyether Block Copolymers.

Authors:  Alaina J McGrath; Weichao Shi; Christina G Rodriguez; Edward J Kramer; Craig J Hawker; Nathaniel A Lynd
Journal:  Polym Chem       Date:  2015-03-07       Impact factor: 5.582

2.  Crystalline CO2-based polycarbonates prepared from racemic catalyst through intramolecularly interlocked assembly.

Authors:  Ye Liu; Wei-Min Ren; Wei-Ping Zhang; Rong-Rong Zhao; Xiao-Bing Lu
Journal:  Nat Commun       Date:  2015-10-15       Impact factor: 14.919

3.  Functionalizable Stereocontrolled Cyclopolyethers by Ring-Closing Metathesis as Natural Polymer Mimics.

Authors:  Mohammed Alkattan; Joëlle Prunet; Michael P Shaver
Journal:  Angew Chem Int Ed Engl       Date:  2018-06-20       Impact factor: 15.336
  3 in total

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