Literature DB >> 20380439

Cationic silane sigma-complexes of ruthenium with relevance to catalysis.

Dmitry V Gutsulyak1, Sergei F Vyboishchikov, Georgii I Nikonov.   

Abstract

Hydrosilylation of carbonyls catalyzed by 2 goes via intermediate formation of cationic silane sigma-complexes 4 which undergo nucleophilic abstraction of the silylium cation studied by DFT calculations.

Entities:  

Year:  2010        PMID： 20380439     DOI： 10.1021/ja101583m

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  3 in total

1.  Insight into catalytic reduction of CO2 to methane with silanes using Brookhart's cationic Ir(iii) pincer complex.

Authors:  Shaoqin Fang; Hongcai Chen; Haiyan Wei
Journal:  RSC Adv       Date:  2018-03-02       Impact factor: 4.036

2.  From a decomposition product to an efficient and versatile catalyst: the [Ru(η5-indenyl)(PPh3)2Cl] story.

Authors:  Simone Manzini; José A Fernández-Salas; Steven P Nolan
Journal:  Acc Chem Res       Date:  2014-09-29       Impact factor: 22.384

3.  Peripheral mechanism of a carbonyl hydrosilylation catalysed by an SiNSi iron pincer complex.

Authors:  Toni T Metsänen; Daniel Gallego; Tibor Szilvási; Matthias Driess; Martin Oestreich
Journal:  Chem Sci       Date:  2015-09-14       Impact factor: 9.825
  3 in total

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