| Literature DB >> 20376304 |
John R Bleeke1, Phawit Putprasert, Todsapon Thananatthanachon, Nigam P Rath.
Abstract
Treatment of aromatic nitriles with methyllithium produces N-lithiated imine reagents which, when reacted with (η(2)-cyclooctene)(Cl)Ir(PMe(3))(3), generate fused iridaazacycles via ortho-metallation. Mono-protonation of these iridaazacycles produces fused iridapyrrole derivatives, while di-protonation leads to several different pathways.Entities:
Year: 2008 PMID： 20376304 PMCID： PMC2850069 DOI： 10.1021/om8008712
Source DB: PubMed Journal: Organometallics ISSN： 0276-7333 Impact factor: 3.876