Literature DB >> 20369208

Deprotonative metallation of ferrocenes using mixed lithium-zinc and lithium-cadmium combinations.

Gandrath Dayaker1, Aare Sreeshailam, Floris Chevallier, Thierry Roisnel, Palakodety Radha Krishna, Florence Mongin.   

Abstract

A mixed lithium-cadmium amide and a combination of lithium and zinc amides were reacted with a range of ferrocenes; deprotonative mono- or dimetallation in general occurred chemoselectively at room temperature, as evidenced by subsequent quenching with iodine.

Entities:  

Year:  2010        PMID： 20369208     DOI： 10.1039/b924939g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  7 in total

1.  Main group multiple C-H/N-H bond activation of a diamine and isolation of a molecular dilithium zincate hydride: experimental and DFT evidence for alkali metal-zinc synergistic effects.

Authors:  Ross Campbell; Daniel Cannon; Pablo García-Álvarez; Alan R Kennedy; Robert E Mulvey; Stuart D Robertson; Jörg Sassmannshausen; Tell Tuttle
Journal:  J Am Chem Soc       Date:  2011-08-04       Impact factor: 15.419

2.  Halide-Mediated Ortho-Deprotonation Reactions Applied to the Synthesis of 1,2- and 1,3-Disubstituted Ferrocene Derivatives.

Authors:  Afrooz Zirakzadeh; Alexander Herlein; Manuela A Groß; Kurt Mereiter; Yaping Wang; Walter Weissensteiner
Journal:  Organometallics       Date:  2015-07-29       Impact factor: 3.876

3.  Crystal structure of ruthenocenecarbo-nitrile.

Authors:  Frank Strehler; Marcus Korb; Heinrich Lang
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2015-03-21

4.  Synergic transformation of an ethylenediamine to a lithium 1,3-diaza-2-zincacyclopentene via an alkyllithium/bis(alkyl)zinc mixture.

Authors:  Ross Campbell; Pablo García-Alvarez; Alan R Kennedy; Robert E Mulvey
Journal:  Chemistry       Date:  2010-09-03       Impact factor: 5.236

5.  Walphos versus Biferrocene-Based Walphos Analogues in the Asymmetric Hydrogenation of Alkenes and Ketones.

Authors:  Afrooz Zirakzadeh; Manuela A Groß; Yaping Wang; Kurt Mereiter; Walter Weissensteiner
Journal:  Organometallics       Date:  2014-04-09       Impact factor: 3.876

6.  Structural Diversity in Alkali Metal and Alkali Metal Magnesiate Chemistry of the Bulky 2,6-Diisopropyl-N-(trimethylsilyl)anilino Ligand.

Authors:  M Ángeles Fuentes; Andoni Zabala; Alan R Kennedy; Robert E Mulvey
Journal:  Chemistry       Date:  2016-08-30       Impact factor: 5.236

7.  Synthesis of Polysubstituted Ferrocenesulfoxides.

Authors:  Min Wen; William Erb; Florence Mongin; Yury S Halauko; Oleg A Ivashkevich; Vadim E Matulis; Thierry Roisnel
Journal:  Molecules       Date:  2022-03-09       Impact factor: 4.411
  7 in total

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