Literature DB >> 20369206

Enantioselective construction of allylic phosphine oxides through substitution of Morita-Baylis-Hillman carbonates with phosphine oxides.

Liang Hong1, Wangsheng Sun, Chunxia Liu, Depeng Zhao, Rui Wang.   

Abstract

The asymmetric organocatalytic allylic substitution reaction of MBH carbonates with phosphine oxides has been developed. This organocatalytic approach constitutes an easy and efficient method for the direct preparation of allylic phosphine oxides in high enantioselectivities.

Entities:  

Mesh：

Substances：

Year:  2010        PMID： 20369206     DOI： 10.1039/b926037d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Nickel/Brønsted acid dual-catalyzed regio- and enantioselective hydrophosphinylation of 1,3-dienes: access to chiral allylic phosphine oxides.

Authors:  Jiao Long; Yuqiang Li; Weining Zhao; Guoyin Yin
Journal:  Chem Sci       Date:  2021-12-28       Impact factor: 9.825

2.  Asymmetric allylic alkylation of Morita-Baylis-Hillman carbonates with α-fluoro-β-keto esters.

Authors:  Lin Yan; Zhiqiang Han; Bo Zhu; Caiyun Yang; Choon-Hong Tan; Zhiyong Jiang
Journal:  Beilstein J Org Chem       Date:  2013-09-11       Impact factor: 2.883
  2 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.