Literature DB >> 20337463

Gold-catalyzed benzannulation of 3-alkoxy-1,5-enynes: access to functionalized benzenes.

Guijie Li1, Yuanhong Liu.   

Abstract

A cationic Au(I) complex catalyzed benzannulation of 3-alkoxy-1,5-enynes bridged by a cyclopropyl ring with a variety of nucleophiles is described. The reaction occurs selectively through a 6-endo-dig pathway to provide tri- and tetrasubstituted benzenes efficiently under mild reaction conditions.

Entities:  

Year:  2010        PMID: 20337463     DOI: 10.1021/jo100137j

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  2 in total

1.  Recent advances in the gold-catalyzed additions to C-C multiple bonds.

Authors:  He Huang; Yu Zhou; Hong Liu
Journal:  Beilstein J Org Chem       Date:  2011-07-04       Impact factor: 2.883

2.  Hydroacenes Made Easy by Gold(I) Catalysis.

Authors:  Ruth Dorel; Paul R McGonigal; Antonio M Echavarren
Journal:  Angew Chem Int Ed Engl       Date:  2016-07-06       Impact factor: 15.336

  2 in total

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