Reaction of a monosubstituted, 1,3-disubstituted, or tetrasubstituted allene with various indoles catalyzed by a 1:1 mixture of a gold(I) N-heterocyclic carbene complex and AgOTf at room temperature leads to hydroarylation with formation of 3-allyl-indoles in modest to good yield.
Reaction of a monosubstituted, 1,3-disubstituted, or tetrasubstituted n class="Chemical">allene with various indoles catalyzed by a 1:1 mixture of a gold(I)N-heterocyclic carbene complex and AgOTf at room temperature leads to hydroarylation with formation of 3-allyl-indoles in modest to good yield.
Authors: Nicholas A Foley; Marty Lail; John P Lee; T Brent Gunnoe; Thomas R Cundari; Jeffrey L Petersen Journal: J Am Chem Soc Date: 2007-05-09 Impact factor: 15.419
Authors: Lisa Cooper; José Miguel Alonso; Louise Eagling; Helen Newson; Sachini Herath; Christopher Thomson; Andrew Lister; Catherine Howsham; Brian Cox; María Paz Muñoz Journal: Chemistry Date: 2018-03-05 Impact factor: 5.236