Hydrochemistry and evaluation of groundwater suitability for irrigation and drinking purposes in the Markandeya River basin, Belgaum District, Karnataka State, India.

Markandeya River basin stretches geographically from 15°56' to 16°08' N latitude and 74°37' to 74°58' E longitude, positioned in the midst of Belgaum district, in the northern part of Karnataka. Since the quantity and quality of water available for irrigation in India is variable from place to place, groundwater quality in the Markandeya River basin was evaluated for its suitability for drinking and irrigation purposes by collecting 47 open and bore-well samples during the post-monsoon period of 2008. The quality assessment was made by estimating pH, electrical conductivity, total dissolved solids, hardness, and alkalinity besides major cations (Na+, K+, Ca2+, and Mg2+) and anions (HCO3-, Cl-, SO4(2-), PO4(3-), F-, and NO3-). Based on these analyses, irrigation quality parameters like, sodium absorption ratio, %Na, residual sodium carbonate, residual sodium bicarbonate, chlorinity index, soluble sodium percentage, non-carbonate hardness, potential salinity, permeability index, Kelley's ratio, magnesium hazard/ratio, index of base exchange, and exchangeable sodium ratio were calculated. According to Gibbs' ratio, majority of water samples fall in the rock dominance field. The groundwater samples were categorized as normal chloride (95.75%), normal sulfate (95.75%), and normal bicarbonate (61.70%) water types based on Cl, SO4, and HCO3 concentrations. Based on the permeability index, majority of the samples belongs to classes 1 and 2, suggesting the suitability of groundwater for irrigation. The negative index of base exchange indicates the existence of chloro-alkaline disequilibrium (indirect base exchange reaction) existing in majority of the samples (68.08%) from the study area.