Literature DB >> 20235546

Phosphorus can also be a "photocopy".

Marlena P Washington1, Vittal B Gudimetla, Feng L Laughlin, Nihal Deligonul, Susan He, John L Payton, M Cather Simpson, John D Protasiewicz.   

Abstract

The syntheses of benzoxaphospholes and new benzobisoxaphospholes that display blue fluorescence are presented. The latter compounds were accessed by the use of a new precursor, 2,5-diphosphinohydroquinone. The new compounds were fully characterized, including a structural study of 2,6-tert-butylbenzo[1,2-d;4,5-d']bisoxaphosphole. Quantum yields for photoluminescence were determined for a series of compounds. These materials feature bona fide P horizontal lineC p-p pi bonds suitable for conjugated materials having phosphorus as a participatory atom and can thus "photocopy" the properties of other conjugated organic molecules.

Entities:  

Year:  2010        PMID: 20235546     DOI: 10.1021/ja1009426

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  3 in total

1.  Reactivity enhancement of a diphosphene by reversible N-heterocyclic carbene coordination.

Authors:  Debabrata Dhara; Pankaj Kalita; Subhadip Mondal; Ramakirushnan Suriya Narayanan; Kaustubh R Mote; Volker Huch; Michael Zimmer; Cem B Yildiz; David Scheschkewitz; Vadapalli Chandrasekhar; Anukul Jana
Journal:  Chem Sci       Date:  2018-03-27       Impact factor: 9.825

2.  A selective route to aryl-triphosphiranes and their titanocene-induced fragmentation.

Authors:  André Schumann; Fabian Reiß; Haijun Jiao; Jabor Rabeah; Jan-Erik Siewert; Ivo Krummenacher; Holger Braunschweig; Christian Hering-Junghans
Journal:  Chem Sci       Date:  2019-07-30       Impact factor: 9.825

3.  Isolation of singlet carbene derived 2-phospha-1,3-butadienes and their sequential one-electron oxidation to radical cations and dications.

Authors:  Mahendra K Sharma; Sebastian Blomeyer; Timo Glodde; Beate Neumann; Hans-Georg Stammler; Alexander Hinz; Maurice van Gastel; Rajendra S Ghadwal
Journal:  Chem Sci       Date:  2020-01-06       Impact factor: 9.825

  3 in total

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