| Literature DB >> 20235546 |
Marlena P Washington1, Vittal B Gudimetla, Feng L Laughlin, Nihal Deligonul, Susan He, John L Payton, M Cather Simpson, John D Protasiewicz.
Abstract
The syntheses of benzoxaphospholes and new benzobisoxaphospholes that display blue fluorescence are presented. The latter compounds were accessed by the use of a new precursor, 2,5-diphosphinohydroquinone. The new compounds were fully characterized, including a structural study of 2,6-tert-butylbenzo[1,2-d;4,5-d']bisoxaphosphole. Quantum yields for photoluminescence were determined for a series of compounds. These materials feature bona fide P horizontal lineC p-p pi bonds suitable for conjugated materials having phosphorus as a participatory atom and can thus "photocopy" the properties of other conjugated organic molecules.Entities:
Year: 2010 PMID: 20235546 DOI: 10.1021/ja1009426
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419