Literature DB >> 20232839

Rhodium-catalyzed reductive allylation of conjugated aldehydes with allyl acetate.

Maksym Vasylyev1, Howard Alper.   

Abstract

Reductive allylation of aryl and alkenyl aldehydes with allyl acetate catalyzed by the ionic diamine carbonyl rhodium complex, [Rh(TMEDA)(CO)(2)][RhCl(2)(CO)(2)], under a carbon monoxide atmosphere afforded the corresponding homoallylic alcohols in good isolated yields.

Entities:  

Year:  2010        PMID： 20232839     DOI： 10.1021/jo902706p

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  5 in total

1.  Catalytic Nucleophilic Allylation Driven by the Water-Gas Shift Reaction.

Authors:  Scott E Denmark; Zachery D Matesich; Son T Nguyen; Selena Milicevic Sephton
Journal:  J Org Chem       Date:  2017-12-08       Impact factor: 4.354

2.  Formation of C-C Bonds via Iridium-Catalyzed Hydrogenation and Transfer Hydrogenation.

Authors:  John F Bower; Michael J Krische
Journal:  Top Organomet Chem       Date:  2011-01-01       Impact factor: 1.311

Review 3.  Harnessing the Power of the Water-Gas Shift Reaction for Organic Synthesis.

Authors:  Andrea Ambrosi; Scott E Denmark
Journal:  Angew Chem Int Ed Engl       Date:  2016-09-06       Impact factor: 15.336

4.  Enthalpy vs Entropy Driven Complexation of Homoallylic Alcohols by Rh(I) Complexes.

Authors:  Sung Ok Kang; Vincent M Lynch; Victor W Day; Eric V Anslyn
Journal:  Organometallics       Date:  2011-10-25       Impact factor: 3.876

5.  Allylation of functionalized aldehydes by potassium allyltrifluoroborate catalyzed by 18-crown-6 in aqueous media.

Authors:  Fernanda C G Barbosa; Juliano C R Freitas; Caio F Melo; Paulo H Menezes; Roberta A Oliveira
Journal:  Molecules       Date:  2012-11-28       Impact factor: 4.411
  5 in total

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