Literature DB >> 20230036

Synthesis of [n]rotaxanes by template-directed clipping: the role of the dialkylammonium recognition sites.

Jun Yin1, Suvankar Dasgupta, Jishan Wu.   

Abstract

Linear and rectangular [n]rotaxanes were synthesized by template-directed clipping of heterocrown ether components onto the dumbbell-shaped molecules containing different dialkylammonium recognition sites. The effect of the structure of the dialkylammonium sites on the clipping efficiency was investigated, and selective clipping led to formation of a rectangular [4]rotaxane.

Entities:  

Year:  2010        PMID: 20230036     DOI: 10.1021/ol100256w

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  {2,6-Bis[(4-bromo-phen-yl)imino-meth-yl]pyridine-κN,N',N''}trichlorido-chromium(III).

Authors:  Xiao-Ping Li; Yong-Yong Liu; Jian-She Zhao
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-09-08

2.  Revisiting the formation and tunable dissociation of a [2]pseudorotaxane formed by slippage approach.

Authors:  Ken Cham-Fai Leung; Kwun-Ngai Lau; Wing-Yan Wong
Journal:  Int J Mol Sci       Date:  2015-04-13       Impact factor: 5.923

  2 in total

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