Literature DB >> 20222710

Self-assembly of molecular cylinders from polycarbene ligands and Ag(I) or Au(I).

Arnab Rit1, Tania Pape, F Ekkehardt Hahn.   

Abstract

Tris- and tetrakis(imidazolium) salts react with Ag(2)O to give cylindrical polynuclear silver(I) complexes such as the tetrasilver derivative [Ag(4)(1)(2)](PF(6))(4). The silver(I) complexes undergo transmetalation with [AuCl(SMe(2))] to yield homonuclear gold(I) complexes with retention of the metallosupramolecular assembly.

Entities:  

Year:  2010        PMID: 20222710     DOI: 10.1021/ja101490d

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  6 in total

1.  NHC-Based Self-Assembled Monolayers on Solid Gold Substrates.

Authors:  Tobias Weidner; Joe E Baio; Alexander Mundstock; Christoph Große; Silvia Karthäuser; Clemens Bruhn; Ulrich Siemeling
Journal:  Aust J Chem       Date:  2011-08-19       Impact factor: 1.321

2.  Well-defined coinage metal transfer agents for the synthesis of NHC-based nickel, rhodium and palladium macrocycles.

Authors:  Rhiann E Andrew; Caroline M Storey; Adrian B Chaplin
Journal:  Dalton Trans       Date:  2016-05-09       Impact factor: 4.390

3.  Confinement of a Au-N-heterocyclic carbene in a Pd6L12 metal-organic cage.

Authors:  Lihua Zeng; Shujian Sun; Zhang-Wen Wei; Yu Xin; Liping Liu; Jianyong Zhang
Journal:  RSC Adv       Date:  2020-10-27       Impact factor: 4.036

4.  Synthesis of N-Heterocyclic Carbenes and Their Complexes by Chloronium Ion Abstraction from 2-Chloroazolium Salts Using Electron-Rich Phosphines.

Authors:  Matthias D Böhme; Tobias Eder; Maike B Röthel; Patrick D Dutschke; Lukas F B Wilm; F Ekkehardt Hahn; Fabian Dielmann
Journal:  Angew Chem Int Ed Engl       Date:  2022-05-17       Impact factor: 16.823

5.  Post-Synthetic Modification of a Porous Hydrocarbon Cage to Give a Discrete Co24 Organometallic Complex.

Authors:  Chriso M Thomas; Weibin Liang; Dan Preston; Christian J Doonan; Nicholas G White
Journal:  Chemistry       Date:  2022-07-21       Impact factor: 5.020

6.  Rhodium, iridium and nickel complexes with a 1,3,5-triphenylbenzene tris-MIC ligand. Study of the electronic properties and catalytic activities.

Authors:  Carmen Mejuto; Beatriz Royo; Gregorio Guisado-Barrios; Eduardo Peris
Journal:  Beilstein J Org Chem       Date:  2015-12-14       Impact factor: 2.883

  6 in total

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