Literature DB >> 20205465

Synthesis of 2-indolylphosphines by palladium-catalyzed annulation of 1-alkynylphosphine sulfides with 2-iodoanilines.

Azusa Kondoh1, Hideki Yorimitsu, Koichiro Oshima.   

Abstract

Palladium-catalyzed annulation of 1-alkynylphosphine sulfides with 2-iodoanilines followed by desulfidation affords 3-substituted 2-indolylphosphines. This annulation/desulfidation sequential protocol offers a conceptually new approach to bulky heteroarylphosphines.

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Year:  2010        PMID： 20205465     DOI： 10.1021/ol1001544

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

1.  Copper-catalyzed stereo- and regioselective hydrophosphorylation of terminal alkynes: scope and mechanistic study.

Authors:  Junchen Li; Zhenhua Gao; Yongbiao Guo; Haibo Liu; Peichao Zhao; Xiaojing Bi; Enxue Shi; Junhua Xiao
Journal:  RSC Adv       Date:  2022-06-29       Impact factor: 4.036

2.  Lewis Acid-Controlled Regioselective Phosphorylation of 2-Indolylmethanols with Diarylphosphine Oxides: Synthesis of Highly Substituted Indoles.

Authors:  Chen Hu; Gang Hong; Yuchen He; Chen Zhou; Marisa C Kozlowski; Limin Wang
Journal:  J Org Chem       Date:  2018-04-04       Impact factor: 4.354

Review 3.  Recent applications of the (TMS)3SiH radical-based reagent.

Authors:  Chryssostomos Chatgilialoglu; Jacques Lalevée
Journal:  Molecules       Date:  2012-01-06       Impact factor: 4.411
  3 in total

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