Literature DB >> 20205421

Hydroformylation reaction of alkylidenecyclopropane derivatives: a new pathway for the formation of acyclic aldehydes containing quaternary stereogenic carbons.

Samah Simaan1, Ilan Marek.   

Abstract

The rhodium-catalyzed hydroformylation reaction of methylene- and alkylidenecyclopropane derivatives proceeds under mild conditions to lead to the exclusive formation of linear aldehydes and the stereointegrity of the quaternary carbon center remains unaffected in the process.

Entities:  

Year:  2010        PMID： 20205421     DOI： 10.1021/ja100544c

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  8 in total

1.  Synthesis of quaternary carbon centers via hydroformylation.

Authors:  X Sun; K Frimpong; K L Tan
Journal:  J Am Chem Soc       Date:  2010-09-01       Impact factor: 15.419

2.  Axial preferences in allylations via the Zimmerman-Traxler transition state.

Authors:  Noga Gilboa; Hao Wang; Kendall N Houk; Ilan Marek
Journal:  Chemistry       Date:  2011-06-03       Impact factor: 5.236

3.  Enantioselective Palladium-Catalyzed Alkenylation of Trisubstituted Alkenols To Form Allylic Quaternary Centers.

Authors:  Harshkumar H Patel; Matthew S Sigman
Journal:  J Am Chem Soc       Date:  2016-10-25       Impact factor: 15.419

4.  Regioselective hydroformylation of allylic alcohols.

Authors:  Thomas E Lightburn; Omar A De Paolis; Ka H Cheng; Kian L Tan
Journal:  Org Lett       Date:  2011-04-19       Impact factor: 6.005

5.  Remote functionalization of hydrocarbons with reversibility enhanced stereocontrol.

Authors:  Alexandre Vasseur; Lionel Perrin; Odile Eisenstein; Ilan Marek
Journal:  Chem Sci       Date:  2015-03-03       Impact factor: 9.825

6.  Efficient and stereodivergent synthesis of unsaturated acyclic fragments bearing contiguous stereogenic elements.

Authors:  Jeffrey Bruffaerts; David Pierrot; Ilan Marek
Journal:  Nat Chem       Date:  2018-08-27       Impact factor: 24.427

7.  Stereoselective Synthesis of Polysubstituted Spiropentanes.

Authors:  Yair Cohen; Dor Toledano; Ilan Marek
Journal:  J Am Chem Soc       Date:  2022-09-11       Impact factor: 16.383

8.  Palladium-catalyzed hydroalkylation of methylenecyclopropanes with simple hydrazones.

Authors:  Jinzhong Yao; Zhangpei Chen; Lin Yu; Leiyang Lv; Dawei Cao; Chao-Jun Li
Journal:  Chem Sci       Date:  2020-05-15       Impact factor: 9.825
  8 in total

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